PT ion: \(H^++OH^-\rightarrow H_2O\)

Ta có: \(\left\{{}\begin{matrix}n_{H^+}=0,2\cdot0,5\cdot2=0,2\left(mol\right)\\n_{OH^-}=0,05\cdot2=0,1\left(mol\right)\end{matrix}\right.\) \(\Rightarrow\) H⁺ còn dư 0,1 mol

\(\Rightarrow\left[H^+\right]=\dfrac{0,1}{0,25}=0,4\left(M\right)\) \(\Rightarrow pH=-log\left(0,4\right)\approx0,4\)

\(n_{H_2SO_4\left(2M\right)}=0,15.2=0,3\left(mol\right)\)

\(n_{H_2SO_4\left(3M\right)}=0,15.3=0,45\left(mol\right)\)

\(n_{H_2SO_4\left(B\right)}=0,3+0,45=0,75\left(mol\right)\)

\(\Rightarrow C_{M_{ddB}}=\dfrac{0,75}{0,2}=3,75M\)

\(n_{H_2SO_4\left(tổng\right)}=0,15.2+0,05.3=0,45\left(mol\right)\\ V_{ddH_2SO_4\left(tổng\right)}=150+50=200\left(ml\right)=0,2\left(l\right)\\ C_{MddH_2SO_4\left(sau\right)}=C_{MddB}=\dfrac{0,45}{0,2}=2,25\left(M\right)\)

\(A/n_{Na_2SO_4}=0,1.2=0,2mol\\ n_{BaCl_2}=0,2.3=0,6mol\\ Na_2SO_4+BaCl_2\rightarrow BaSO_4+2NaCl\\ \Rightarrow\dfrac{0,2}{1}< \dfrac{0,6}{1}\Rightarrow BaCl_2.dư\\ Na_2SO_4+BaCl_2\rightarrow BaSO_4+2NaCl\)

0,2mol          0,2mol        0,2mol          0,4mol

\(m_{rắn}=m_{BaSO_4}=0,2.233=46,6g\\ B/C_{M_{NaCl}}=\dfrac{0,4}{0,1+0,2}=\dfrac{4}{3}M\\ C_{M_{BaCl_2}}=\dfrac{0,6-0,2}{0,1+0,2}=\dfrac{4}{3}M\)

\(n_{Na_2SO_4}=0,1.2=0,2\left(mol\right);n_{BaCl_2}=0,2.3=0,6\left(mol\right)\\ PTHH:Na_2SO_4+BaCl_2\rightarrow BaSO_4\downarrow+2NaCl\\ Vì:\dfrac{0,2}{1}< \dfrac{0,6}{1}\rightarrow BaCl_2dư\\ n_{BaSO_4}=n_{BaCl_2\left(p.ứ\right)}=n_{Na_2SO_4}=0,2\left(mol\right)\\ a,m_{rắn}=m_{BaSO_4}=233.0,2=46,6\left(g\right)\)

b, Dung dịch sau phản ứng có: NaCl và BaCl₂ dư

\(n_{BaCl_2\left(dư\right)}=0,6-0,2=0,4\left(mol\right)\\ n_{NaCl}=0,2.2=0,4\left(mol\right)\\V_{ddsau}=0,1+0,2=0,3\left(mol\right)\\ C_{MddBaCl_2}=\dfrac{0,4}{0,3}=\dfrac{4}{3}\left(M\right);C_{MddNaCl}=\dfrac{0,4}{0,3}=\dfrac{4}{3}\left(M\right)\)

a, \(n_{NaOH}=0,02.1,5=0,03\left(mol\right);n_{HCl}=0,03.2=0,06\left(mol\right)\)

PTHH: NaOH + HCl → NaCl + H₂O

Mol:      0,03     0,03       0,03

Ta có: \(\dfrac{0,03}{1}< \dfrac{0,06}{1}\) ⇒ NaOH hết, HCl dư

\(m_{NaCl}=0,03.58,5=1,755\left(g\right)\)

b, m_{dd sau pứ} = 0,02 + 0,03 = 0,05 (l)

\(C_{M_{ddNaCl}}=\dfrac{0,03}{0,05}=0,6M\)

\(C_{M_{ddHCl}}=\dfrac{\left(0,06-0,03\right)}{0,05}=0,6M\)

a. PT: NaOH + HCl ---> NaCl + H₂O

Đổi 20ml = 0,02 lít; 30ml = 0,03 lít

Ta có: \(C_{M_{NaOH}}=\dfrac{n_{ct}}{V_{dd}}=\dfrac{n_{NaOH}}{0,02}=1,5M\)

=> n_NaOH = 0,03(mol)

Ta có: \(C_{M_{HCl}}=\dfrac{n_{ct}}{V_{dd}}=\dfrac{n_{HCl}}{0,03}=2M\)

=> n_HCl = 0,06(mol)

Ta có: \(\dfrac{0,03}{1}< \dfrac{0,06}{1}\)

Vậy HCl dư

Theo PT: n_NaCl = n_NaOH = 0,03(mol)

=> m_NaCl = 0,03 . 58,5 = 1,755(g)

a, \(2KOH+MgSO_4\rightarrow K_2SO_4+Mg\left(OH\right)_2\)

b, Ta có: \(n_{KOH}=0,2.1=0,2\left(mol\right)\)

Theo PT: \(n_{MgSO_4}=n_{K_2SO_4}=n_{Mg\left(OH\right)_2}=\dfrac{1}{2}n_{KOH}=0,1\left(mol\right)\)

\(\Rightarrow m_{Mg\left(OH\right)_2}=0,1.58=5,8\left(g\right)\)

c, \(V_{MgSO_4}=\dfrac{0,1}{2}=0,05\left(l\right)\)

d, \(C_{M_{K_2SO_4}}=\dfrac{0,1}{0,2+0,05}=0,4\left(M\right)\)

pt: \(H_2SO_4+2NaOH\rightarrow Na_2SO_4+2H_2O\) (1)

\(H_2SO_4+2KOH\rightarrow K_2SO4+2H2O\) (2)

Do sau phản ứng (1) quỳ tím chuyển thành màu đỏ =>H2SO4 dư

nH2SO4 ban đầu=0,05.1=0,05(mol)

nKOH=0,02.0,5=0,01(mol)

Theo pt (2) : nH2SO4(2)=1/2nKOH=0,005(mol)

=>nH2SO4(1) p/ứ=0,05-0,005=0,045(mol)

Theo pt (1): nNaOH=2nH2SO4=0,09(mol)

=>CM(NaOH)=0,09/0,05=1,8(M)

nH2SO4=0.05*1=0.05 mol

Vì dd sau pư làm đỏ quỳ tím => H2SO4 dư

nKOH= 0.02*0.5=0.01 mol

PTHH: H2SO4 + 2NaOH ----> Na2SO4 + H2O (1)

0.045

H2SO4 + 2KOH ----> K2SO4 + H2O(2)

0.005 0.01

Xét (2) : nH2SO4_dư= 1/2 nKOH= 0.005 mol

=> nH2SO4_{pư (1)}= 0.05-0.005=0.045 mol

Xét (1) : nNaOH =2 nH2SO4= 0.045*2= 0.09 mol

=>CM NaOH= 0.09/0.05=1.8M

Xin lỗi, tôi trả lời chậm quá.... Nhưng thú vị là bn đặt câu hỏi đúng sinh nhật của tôi đấy :)