\(\left\{{}\begin{matrix}Fe\\Al\end{matrix}\right.+HCl->\left\{{}\begin{matrix}FeCl2\\AlCl3\end{matrix}\right.+H2\)

Ta có số mol Fe là x , Al là y (mol)

\(\left\{{}\begin{matrix}56x+27y=11\\127x+133,5y=39,4\end{matrix}\right.\Leftrightarrow\left\{{}\begin{matrix}x=0,1\\y=0,2\end{matrix}\right.\)

\(\Rightarrow\left\{{}\begin{matrix}\%mFe=\dfrac{0,1.56}{11}=50,9\%\\\%mAl=\dfrac{0,2.27}{11}=49,09\%\end{matrix}\right.\)

Bảo toàn e :

\(2.nH2=2.nFe+3.nAl\Rightarrow nH2=0,4\left(mol\right)\)

\(V=0,4.22,4=8,96\left(l\right)\)

\(nFe=nFeCl2=0,1\left(mol\right)\)

\(nAl=nAlCl3=0,2\left(mol\right)\)

\(\Rightarrow nHCl\left(pứ\right)=2.0,1+3.0,2=0,8\left(mol\right)\)

\(Cm=\dfrac{n}{V}=\dfrac{0,8}{0,2}=4\left(M\right)\)

Đáp án D

Gọi a, b lần lượt là mol của Al và Zn

\(2Al+6HCl\rightarrow2AlCl_3+3H_2\)

a                                        1,5a

\(Zn+2HCl\rightarrow ZnCl_2+H_2\)

b                                       b

\(\Rightarrow\left\{{}\begin{matrix}27a+65b=9,2\\1,5a+b=\dfrac{5,6}{22,4}\end{matrix}\right.\)                \(\Leftrightarrow\left\{{}\begin{matrix}a=0,1\\b=0,1\end{matrix}\right.\)

\(\%m_{Al}=\dfrac{0,1.27}{9,2}.100\%=29,35\%\)

\(\%m_{Zn}=\dfrac{0,1.65}{9,2}.100\%=70,35\%\)

b. \(n_{H_2}=0,25mol\)           \(\Rightarrow n_{HCl}=0,5mol\)

\(\Rightarrow m_{HCl}=0,5.36,5=18,25g\)

Ta có:  \(10\%=\dfrac{18,25}{m_{dd}}.100\%\)

\(\Leftrightarrow m_{dd}=182,5g\)

Gọi \(n_{Fe}=x\left(mol\right)\)\(;n_{Zn}=y\left(mol\right)\)

\(n_{H_2}=\dfrac{6,72}{22,4}=0,3mol\)

Ta có:  \(\left\{{}\begin{matrix}56x+65y=18,6\\2x+2y=2n_{H_2}=0,6\end{matrix}\right.\)\(\Rightarrow\left\{{}\begin{matrix}x=0,1\\y=0,2\end{matrix}\right.\)

\(\%m_{Fe}=\dfrac{0,1\cdot56}{18,6}\cdot100\%=30,11\%\)

\(\%m_{Zn}=100\%-30,11\%=69,89\%\)

\(Fe+2HCl\rightarrow FeCl_2+H_2\)

0,1     0,2

\(Zn+2HCl\rightarrow ZnCl_2+H_2\)

0,2     0,4

\(n_{HCl}=0,2+0,4=0,6mol\)

\(C_M=\dfrac{n}{V}=\dfrac{0,6}{0,2}=3M\)

n A l   :   n A l 2 O 3   =   2   :   3 n A l = 2 n H 2 3 = 0 , 02 ⇒ n A l 2 o 3 = 0 , 03

Sơ đồ:

⇒ n H C l = 0 , 07   +   ( 0 , 08 - 0 , 07 ) . 4   =   0 , 11 ⇒ [ H C l ]   = 0 , 11 0 , 2 = 0 , 55

Đáp án C

a, \(Mg+2HCl\rightarrow MgCl_2+H_2\)

\(Fe+2HCl\rightarrow FeCl_2+H_2\)

Gọi: \(\left\{{}\begin{matrix}n_{Mg}=x\left(mol\right)\\n_{Fe}=y\left(mol\right)\end{matrix}\right.\) ⇒ 24x + 56y = 8 (1)

Theo PT: \(\left\{{}\begin{matrix}n_{MgCl_2}=n_{Mg}=x\left(mol\right)\\n_{FeCl_2}=n_{Fe}=y\left(mol\right)\end{matrix}\right.\) ⇒ 95x + 127y = 22,2 (2)

Từ (1) và (2) ⇒ x = y = 0,1 (mol)

\(\Rightarrow\left\{{}\begin{matrix}\%m_{Mg}=\dfrac{0,1.24}{8}.100\%=30\%\\\%m_{Fe}=70\%\end{matrix}\right.\)

b, \(n_{HCl}=2n_{Mg}+2n_{Fe}=0,4\left(mol\right)\)

\(\Rightarrow V_{ddHCl}=\dfrac{0,4}{1}=0,4\left(l\right)\)