nCuO=0,04 mol

CuO        + H2SO4 =>CuSO4 + H2O

0,04 mol=>0,04 mol=>0,04 mol

mH2SO4=0,04.98=3,92 gam

=>m dd H2SO4=3,92/4,9%=80 gam

mCuSO4 sau=0,04.160=6,4 gam

mdd CuSO4=3,2+80=83,2 gam

C% dd CuSO4=6,4/83,2.100%=7,69%

_{cho \(m_{CuO}=3,2g\Rightarrow n_{CuO}=\frac{3,2}{80}=0,04mol\)}

PTHH: 

  CuO           +          H₂SO₄       ->    CuSO₄    +   H₂O

0,04mol----------->0,04mol--------->0,04mol

ta có: \(m_{H_2SO_4}=0,04.98=3,92g\)

\(C\%_{d^2H_2SO_{4_{ }}}=4,9\%\)

=. \(m_{d^2H_2SO_4}=\frac{m_{H_2SO_4}.100}{C\%}=\frac{3,92.100}{4,9}=80g\) 

áp dụng ĐLBTKL ta có: \(m_{d^2CUSO_4}=m_{CuO}+m_{d^2H_2SO_4}=3,2+80=83,2g\)

\(m_{CuSO_4}=0,04.160=6,4g\)

\(\Rightarrow C\%_{d^2CuSO_4}=\frac{m_{CuSO_4}}{m_{d^2CuSO_4}}.100=\frac{6,4}{83,2}.100=7,69\%\)

nCuO=3,2:80=0,04 mol

PTHH: CuO+H2SO4=>CuSO4+H2O

       0,04mol->0,04mol->0,04mol->0,04mol

=>  m H2SO4=0,04.98=3,92g

=> m ddH2SO4 tham gia phản ứng =\(\frac{3,92.100}{4,9}=80\)g

 theo địnhluật bảo toàn khối lượng => m CuSO4= mCuO+mH2SO4-mH2O=3,2+80-0,04.18=82,48g

m CuSO4 thu được= 0,04.160=6,4g

=> C% CuSO4 =\(\frac{6,4}{82,48}.100=7,76\%\)

:)

a) \(n_{Mg}=\dfrac{2,4}{24}=0,1\left(mol\right)\)

PTHH: Mg + H₂SO₄ --> MgSO₄ + H₂

           0,1---->0,1------->0,1---->0,1

=> \(m_{dd.H_2SO_4}=\dfrac{0,1.98}{4,9\%}=200\left(g\right)\)

b) m_{dd sau pư} = 2,4 + 200 - 0,1.2 = 202,2 (g)

m_MgSO4 = 0,1.120 = 12 (g)

\(C\%_{MgSO_4}=\dfrac{12}{202,2}.100\%=5,9\%\)

c) 

\(n_{CuO}=\dfrac{20}{80}=0,25\left(mol\right)\)

PTHH: CuO + H₂ --t^o--> Cu + H₂O

Xét tỉ lệ: \(\dfrac{0,25}{1}>\dfrac{0,1}{1}\) => Hiệu suất tính theo H₂

\(n_{Cu}=\dfrac{3,2}{64}=0,05\left(mol\right)\)

PTHH: CuO + H₂ --t^o--> Cu + H₂O

                      0,05<-----0,05

=> \(H=\dfrac{0,05}{0,1}.100\%=50\%\)

a, \(n_{Mg}=\dfrac{2,4}{24}=0,1\left(mol\right)\)

PTHH: Mg + H₂SO₄ ---> MgSO₄ + H₂

           0,1--->0,1---------->0,1-------->0,1

\(m_{dd\left(H_2SO_4\right)}=\dfrac{0,1.98}{4,9\%}=200\left(g\right)\)

b, \(m_{dd\left(sau.pư\right)}=2,4+200-0,2.2=202,2\left(g\right)\)

\(\rightarrow C\%_{MgSO_4}=\dfrac{0,1.120}{202,2}.100\%=5,93\%\)

c, \(n_{CuO}=\dfrac{20}{80}=0,25\left(mol\right)\)

PTHH: CuO + H₂ --t^o--> Cu + H₂O

LTL: 0,25 > 0,1 => CuO dư

\(n_{Cu}=\dfrac{3,2}{64}=0,05\left(mol\right)\)

Theo pt: \(n_{H_2}=n_{Cu}=0,05\left(mol\right)\)

=> \(H=\dfrac{0,05}{0,1}.100\%=50\%\)

\(n_{CuO}=\dfrac{3,2}{80}=0,04\left(mol\right)\\ pthh:CuO+H_2SO_4\rightarrow CuSO_4+H_2O\) 
           0,04       0,04           0,04      0,04 
\(m_{\text{dd}_{H_2SO_4}}=\dfrac{\left(0,04.36,5\right).100}{4,9}=29,79\left(g\right)\\ m_{\text{dd}_{CuSO_4}}=3,2+29,79-\left(0,04.2\right)=32,91\left(g\right)\\ C\%_{\text{dd}}=\dfrac{0,04.160}{32,91}.100\%=19,44\%\)

n CUO = 16/80 = 0,2 mol
CuO + H2SO4 --> CUSO4 + H2O
0,2 0,2 0,2

C% H2SO4 = 0,2 .98.100%/ m dd H2SO4 = 10%
=> m dd H2SO4 = 196 g
=> m dd sau pư = 196 + 16 = 212 g
m CuSO4 = 0,2,160 =32 g
=> C% dd sau pư = 32 .100% / 212 =15,1%

nCuO = 0.2 mol

CuO + H2SO4 --> CuSO4 + H2O

0.2_____0.2_______0.2

mH2SO4 = 0.2*98 = 19.6 g

mdd H2SO4 = 19.6*100/10 = 196 g

mdd sau phản ứng = 16 + 196 = 212 g

mCuSO4 = 0.2*160 = 32 g

C%CuSO4 = 32/212*100% = 15.09%

n_CuO = 0,2(mol)

CuO + H2SO4 -> CuSO4 + H2O

0,2.........0,2...........0,2 (mol)

m_{dung dịch sau} = 16+ \(\frac{0,2.98}{10\%}=212\left(g\right)\)

C% = \(\frac{0,2.160}{212}.100\%\approx15,09\%\)

a) Na₂CO₃ + 2CH₃COOH --> 2CH₃COONa + CO₂ + H₂O

b) \(n_{CH_3COOH}=\dfrac{25.6\%}{60}=0,025\left(mol\right)\)

PTHH: Na₂CO₃ + 2CH₃COOH --> 2CH₃COONa + CO₂ + H₂O

              0,0125<-----0,025------------>0,025------>0,0125

=> \(m_{Na_2CO_3}=0,0125.106=1,325\left(g\right)\)

c) \(m_{dd.sau.pư}=1,325+25-0,0125.44=25,775\left(g\right)\)

\(C\%_{dd.CH_3COONa}=\dfrac{0,025.82}{25,775}.100\%=7,95\%\)

m CH3COOH=1,5g=>n=0,025 mol

2CH3COOH+Na2CO3->2CH3COONa+H2O+CO2

0,025--------------0,0125----------0,025

=>m Na2CO3=0,0125.106=1,325g

=>mdd=25g

c) 

C% =\(\dfrac{0,025.82}{25+25}100=4,1\%\)

PTHH: \(2Al+3H_2SO_4\rightarrow Al_2\left(SO_4\right)_3+3H_2\uparrow\)

               2a______3a__________a_______3a    (mol)

            \(Mg+H_2SO_4\rightarrow MgSO_4+H_2\uparrow\)

                b_______b________b______b        (mol)

Ta lập HPT: \(\left\{{}\begin{matrix}27\cdot2a+24b=7,8\\3a+b=\dfrac{200\cdot19,6\%}{98}=0,4\end{matrix}\right.\) \(\Leftrightarrow\left\{{}\begin{matrix}a=0,1\\b=0,1\end{matrix}\right.\)

\(\Rightarrow\left\{{}\begin{matrix}m_{Mg}=0,1\cdot24=2,4\left(g\right)\\m_{Al}=5,4\left(g\right)\\n_{Al_2\left(SO_4\right)_3}=0,1\left(mol\right)=n_{MgSO_4}\\n_{H_2}=0,4\left(mol\right)\Rightarrow m_{H_2}=0,4\cdot2=0,8\left(g\right)\end{matrix}\right.\)

Mặt khác: \(m_{dd}=m_{KL}+m_{ddH_2SO_4}-m_{H_2}=207\left(g\right)\)

\(\Rightarrow\left\{{}\begin{matrix}C\%_{Al_2\left(SO_4\right)_3}=\dfrac{0,1\cdot342}{207}\cdot100\%\approx16,52\%\\C\%_{MgSO_4}=\dfrac{0,1\cdot120}{207}\cdot100\%\approx5,8\%\end{matrix}\right.\)

nFe = 5,6/56 = 0,1 (mol)

Fe + H2SO4 --> FeSO4 + H2

0,1      0,1           0,1          0,1 

VH2 = 0,1.22,4 = 2,24 (l)

mddH2SO4(cần dùng ) = \(\dfrac{0,1.98.100\%}{4,9\%}=200\left(g\right)\)

mH2 = 0,1.2=0,2 (g)

mdd = mFe + mddH2SO4 - mH2 = 5,6 + 200 - 0,2 = 205,4 (g)

mFeSO4 = 0,1.152 = 15,2(g)

=> \(C\%_{ddFeSO_4}=\dfrac{15,2.100}{205,4}=7,4\%\)