câu 1 : ta có : \(\dfrac{2NaOH}{0,03}\dfrac{+}{ }\dfrac{H_2SO_4}{0,0225}\dfrac{\rightarrow}{ }\dfrac{Na_2SO_4}{ }\dfrac{+}{ }\dfrac{2H_2O}{ }\)

\(\Rightarrow NaOH\) phản ứng hết và \(H_2SO_4\) dư \(0,0075\left(mol\right)\)

\(\Rightarrow\dfrac{H_2SO_4}{0,0075}\dfrac{\rightarrow}{ }\dfrac{2H^+}{0,015}\dfrac{+}{ }\dfrac{SO_4^{2-}}{ }\) \(\Rightarrow\left[H^+\right]=\dfrac{0,015}{0,03}=0,5\)

vậy .................................................................................................

câu 2 : ta có : \(\dfrac{2KOH}{0,1}\dfrac{+}{ }\dfrac{H_2SO_4}{0,05}\dfrac{\rightarrow}{ }\dfrac{k_2SO_4}{0,05}\dfrac{+}{ }\dfrac{2H_2O}{0,1}\)

\(\Rightarrow m_{chấtrắng}=m_{K_2SO_4}+m_{KOH_{dư}}\) \(\Leftrightarrow m_{KOH_{dư}}=m_{chấtrắng}-m_{K_2SO_4}\)

\(\Leftrightarrow m_{KOH_{dư}}=11,5-0,05.174=2,8\)

\(\Rightarrow m_{KOH}=0,1.56+2,8=3,36\) \(\Rightarrow n_{KOH}=\dfrac{3,36}{56}=0,06\)

\(\Rightarrow C_M=\dfrac{0,06}{0,15}=0,4\left(M\right)\)

vậy .................................................................................................

\(\left[Na^+\right]=\dfrac{2.0,015}{2.0,015}=1M\)

\(\left[OH^-\right]=\dfrac{2.0,015}{2.0,015}=1M\)

\(\left[H^+\right]=\dfrac{2.1,5.0,015}{2.0,015}=1,5M\)

\(\left[SO_4^{2-}\right]=\dfrac{1,5.0,015}{2.0,015}=0,75M\)

\(n_{NaOH}=0,015.2=0,03\left(mol\right)\)

\(n_{H_2SO_4}=0,01.1,5=0,015\left(mol\right)\)

PTHH: \(2NaOH+H_2SO_4\rightarrow Na_2SO_4+2H_2O\)

Xét: \(\frac{n_{NaOH}}{2}=0,015=\frac{n_{H_2SO_4}}{1}=0,015\)\

=> NaOH và H₂SO₄ vừa đủ

=> Dung dịch sau phản ứng trung hòa

\(n_{NaOH}=0,2.1=0,2\left(mol\right)\\ n_{H_2SO_4}=0,3.1,5=0,45\left(mol\right)\)

\(2NaOH+H_2SO_4\rightarrow Na_2SO_4+2H_2O\)

0,2------->0,1--------->0,1

Xét \(\dfrac{0,2}{2}< \dfrac{0,45}{1}\Rightarrow\) \(H_2SO_4\)dư

Trong dung dịch D có:

\(\left\{{}\begin{matrix}n_{H_2SO_4}=0,45-0,1=0,35\left(mol\right)\\n_{Na_2SO_4}=0,1\left(mol\right)\end{matrix}\right.\)

\(\Rightarrow\left\{{}\begin{matrix}CM_{H_2SO_4}=\dfrac{0,35}{0,5}=0,7M\\CM_{Na_2SO_4}=\dfrac{0,1}{0,5}=0,2M\end{matrix}\right.\)

b

\(Ca\left(OH\right)_2+H_2SO_4\rightarrow CaSO_4+2H_2O\)

0,35<---------0,35

\(V_{Ca\left(OH\right)_2}=\dfrac{0,35.74}{1,2}=\dfrac{259}{12}\approx21,58\left(ml\right)\\ \Rightarrow V_{dd.Ca\left(OH\right)_2}=\dfrac{\dfrac{259}{12}.100\%}{10\%}=\dfrac{1295}{6}\approx215,83\left(ml\right)\)

Ta có: \(n_{HCl}=0,15\cdot1,5+0,1\cdot2=0,425\left(mol\right)\)

\(\Rightarrow C_{M_{HCl}}=\dfrac{0,425}{0,15+0,1}=1,7\left(M\right)\)

+) Ta có:

 `V(dd(H_2SO_4)(1))=300(ml)=0,3(l)`

`V(dd(H_2SO_4)(2))=200(ml)=0,2(l)`

`=> n_((H_2SO_4)(1))=0,3.2=0,6(mol)`

 `->n_((H_2SO_4)(2))=0,2.1=0,2(mol)`

=> Nồng độ mol của dung dịch H2SO4 sau trộn:

`CM_(ddH2SO4(mới))=((0,6+0,2)/(0,3+0,2))=1,6M`

`#BTrancuato<3`