a, Giả sử: \(\left\{{}\begin{matrix}n_{Mg}=x\left(mol\right)\\n_{MgO}=y\left(mol\right)\end{matrix}\right.\)
\(\Rightarrow24x+40y=4\left(1\right)\)
Ta có: \(n_{N_2}=\frac{0,672}{22,4}=0,03\left(mol\right)\)
Các quá trình:
\(Mg^0\rightarrow Mg^{+2}+2e\)
x ______________ 2x (mol)
\(2N^{+5}+10e\rightarrow N^0_2\)
________ 0,3 __ 0,03 (mol)
Theo ĐLBT mol e, có: 2x = 0,3 (2)
Từ (1) và (2) \(\Rightarrow\left\{{}\begin{matrix}x=0,15\left(mol\right)\\y=0,01\left(mol\right)\end{matrix}\right.\)
\(\Rightarrow\left\{{}\begin{matrix}m_{Mg}=0,15.24=3,6\left(g\right)\\m_{MgO}=0,01.40=0,4\left(g\right)\end{matrix}\right.\)
b, BTNT Mg, có: \(n_{Mg\left(NO_3\right)_2}=n_{Mg}+n_{MgO}=0,16\left(mol\right)\)
\(\Sigma n_{HNO_3}=2n_{Mg\left(NO_3\right)_2}+2n_{N_2}=0,38\left(mol\right)\)
\(\Rightarrow m_{HNO_3}=0,38.63=23,94\left(g\right)\)
\(\Rightarrow m_{ddHNO_3}=\frac{23,94.100}{40}=59,85\left(g\right)\)
c, Ta có: m dd sau pư = mG + m dd HNO3 - mN2
= 4 + 59,85 - 0,03.28
= 63,01 (g)
\(\Rightarrow C\%_{Mg\left(NO_3\right)_2}=\frac{0,16.148}{63,01}.100\%\approx37,58\%\)
Bạn tham khảo nhé!
