Hóa học

\(\left(1\right)2KMnO_4\underrightarrow{t^0}K_2MnO_4+MnO_2+O_2\\ \left(2\right)4P+5O_2\underrightarrow{t^0}2P_2O_5\\ \left(3\right)P_2O_5+3H_2O\xrightarrow[]{}2H_3PO_4\)

`C_6 H_12 O_6 -\text{lên men}-> 2C_2 H_5 OH+2CO_2 \uparrow`

        `0,3`                                 `0,6`                `0,6`       

`n_[CO_2]=[13,8]/[22,4]=0,6(mol)`

`a)C_[M_[C_6 H_12 O_6]]=[0,3]/[0,3]=1(M)`

`b)m_[C_2 H_5 OH]=0,6.46=27,6(g)`

`c)m_[C_6 H_12 O_6 (bđ)]=0,3. 100/95 .180=56,84(g)`

a, \(C_2H_4+Br_2\rightarrow C_2H_4Br_2\)

\(C_2H_2+2Br_2\rightarrow C_2H_2Br_4\)

Ta có: \(n_{C_2H_4}+n_{C_2H_2}=\dfrac{8,96}{22,4}=0,4\left(mol\right)\left(1\right)\)

Theo PT: \(n_{Br_2}=n_{C_2H_4}+2n_{C_2H_2}=0,25.2=0,5\left(mol\right)\left(2\right)\)

Từ (1) và (2) \(\Rightarrow\left\{{}\begin{matrix}n_{C_2H_4}=0,3\left(mol\right)\\n_{C_2H_2}=0,1\left(mol\right)\end{matrix}\right.\)

\(\Rightarrow\left\{{}\begin{matrix}\%V_{C_2H_4}=\dfrac{0,3.22,4}{8,96}.100\%=75\%\\\%V_{C_2H_2}=25\%\end{matrix}\right.\)

b, Theo PT: \(\left\{{}\begin{matrix}n_{C_2H_4Br_2}=n_{C_2H_4}=0,3\left(mol\right)\\n_{C_2H_2Br_4}=n_{C_2H_2}=0,1\left(mol\right)\end{matrix}\right.\)

\(\Rightarrow\left\{{}\begin{matrix}m_{C_2H_4Br_2}=0,3.188=56,4\left(g\right)\\m_{C_2H_2Br_4}=0,1.346=34,6\left(g\right)\end{matrix}\right.\)

\(V_{HCl}=200ml=0,2l\\ n_{Mg}=\dfrac{6}{24}=0,25\left(mol\right)\\ PTHH:Mg+2HCl\xrightarrow[]{}MgCl_2+H_2\\ n_{HCl}=0,25.2=0,5\left(mol\right)\\ C_{MHCl}=\dfrac{0,5}{0,2}=2,5\left(M\right)\)

\(n_{Mg}=\dfrac{6}{24}=0,25\left(mol\right)\)

PT: \(Mg+2HCl\rightarrow MgCl_2+H_2\)

Theo PT: \(n_{MgCl_2}=n_{Mg}=0,25\left(mol\right)\)

\(\Rightarrow C_{M_{MgCl_2}}=\dfrac{0,25}{0,2}=1,25\left(M\right)\)

Ta có: \(C\%_{NaNO_3}=\dfrac{10}{10+360}.100\%\approx2,7\%\)

a, Ta có: 24n_Mg + 56n_Fe = 9,2 (g) (1)

\(n_{H_2}=\dfrac{5,6}{22,4}=0,25\left(mol\right)\)

BT e, có: 2n_Mg + 2n_Fe = 2n_H2 = 0,5 (2)

Từ (1) và (2) \(\Rightarrow\left\{{}\begin{matrix}n_{Mg}=0,15\left(mol\right)\\n_{Fe}=0,1\left(mol\right)\end{matrix}\right.\)

\(\Rightarrow\left\{{}\begin{matrix}\%m_{Mg}=\dfrac{0,15.24}{9,2}.100\%\approx39,13\%\\\%m_{Fe}\approx60,87\%\end{matrix}\right.\)

b, BTNT H, có: \(n_{HCl}=2n_{H_2}=0,5\left(mol\right)\Rightarrow C_{M_{HCl}}=\dfrac{0,5}{0,2}=2,5\left(M\right)\)

Gọi $n_{Mg} = a(mol) ; n_{Zn} = b(mol) \Rightarrow 24a + 65b = 15,3(1)$
$Mg + 2HCl \to MgCl_2 + H_2$
$Zn + 2HCl \to ZnCl_2 + H_2$
Theo PTHH : $n_{H_2} = a + b = \dfrac{6,72}{22,4} = 0,3(2)$

Từ (1)(2) suy ra : $a = \dfrac{81}{410} ; b = \dfrac{21}{205}$

$m_{Mg} = \dfrac{81}{410}.24 = 4,74(gam)$
$m_{Zn} = 15,3 - 4,74 = 10,56(gam)$

$n_{CO_2} = 0,1(mol) ; n_{H_2O} = 0,1(mol)$

Bảo toàn nguyên tố với C, H : 

$n_C = n_{CO_2} = 0,1(mol)$
$n_H = 2n_{H_2O} = 0,2(mol)$

$\Rightarrow n_O = \dfrac{6 - 0,1.12 - 0,2.1}{16} = 0,2875(mol)$
$n_C : n_H : n_O = 0,1 : 0,2 : 0,2875 = 1 : 2 : 2,875$

(Sai đề)