Ta có: \(n_{KOH}=n_{H_2SO_4}=0,25\left(mol\right)\)
PT: \(2KOH+H_2SO_4\rightarrow K_2SO_4+2H_2O\)
Xét tỉ lệ: \(\dfrac{0,25}{2}< \dfrac{0,25}{1}\), ta được H2SO4 dư.
Theo PT: \(n_{H_2SO_4\left(pư\right)}=\dfrac{1}{2}n_{KOH}=0,125\left(mol\right)\)
\(\Rightarrow n_{H_2SO_4\left(dư\right)}=0,25-0,125=0,125\left(mol\right)\)
\(\Rightarrow n_{H^+}=0,125.2=0,25\left(mol\right)\)
\(\Rightarrow\left[H^+\right]=\dfrac{0,25}{0,25+0,25}=0,5\left(M\right)\)
\(\Rightarrow pH=-\log\left(0,5\right)\approx0,3\)
→ Vậy: Dd sau pư có MT axit.