a)
\(n_{H_2} = \dfrac{3,36}{22,4} = 0,15(mol)\\ n_{Mg} = a\ mol; n_{Fe} = b\ mol\\ Mg + 2HCl \to MgCl_2 + H_2\\ Fe + 2HCl \to FeCl_2 + H_2 \)
Theo PTHH, ta có:
\(\left\{{}\begin{matrix}24a+56b=5,2\\a+b=0,15\end{matrix}\right.\Rightarrow\left\{{}\begin{matrix}a=0,1\\b=0,05\end{matrix}\right.\)
Suy ra:
\(\%m_{Mg} = \dfrac{0,1.24}{5,2}.100\% = 46,15\%\\ \%m_{Fe} = 100\% - 46,15\% = 53,85\% \)
b)
\(n_{HCl} = 2n_{H_2} = 0,15.2 = 0,3(mol)\\ \Rightarrow V_{dd\ HCl} = \dfrac{0,3}{1} = 0,3(lít) \)
Đặt :
nMg = a mol
nFe= b mol
mhh = 24a + 56b = 5.2 (g) (1)
Mg + 2HCl => MgCl2 + H2
Fe + 2HCl => FeCl2 + H2
nH2 = a + b = 0.15 (2)
(1) , (2)
a = 0.1
b = 0.05
%Mg = 2.4/5.2 * 100% = 46.15%
%Fe = 100 - 46.15 = 53.85%
nHCl = 2a + 2b = 0.05 * 2 + 0.1*2 = 0.3 (mol)
VddHCl = 0.3/1=0.3 (l)
PTHH: \(Fe+2HCl\rightarrow FeCl_2+H_2\uparrow\) (1)
\(Mg+2HCl\rightarrow MgCl_2+H_2\uparrow\) (2)
a) Ta có: \(\Sigma n_{H_2}=\dfrac{3,36}{22,4}=0,15\left(mol\right)\)
Gọi số mol của Fe là \(a\) \(\Rightarrow n_{H_2\left(1\right)}=a\)
Gọi số mol của Mg là b \(\Rightarrow n_{H_2\left(2\right)}=b\)
Ta lập được hệ phương trình:
\(\left\{{}\begin{matrix}56a+24b=5,2\\a+b=0,15\end{matrix}\right.\) \(\Leftrightarrow\left\{{}\begin{matrix}a=0,05\\b=0,1\end{matrix}\right.\) \(\Rightarrow\left\{{}\begin{matrix}m_{Fe}=0,05\cdot56=2,8\left(g\right)\\m_{Mg}=0,1\cdot24=2,4\left(g\right)\end{matrix}\right.\)
\(\Rightarrow\left\{{}\begin{matrix}\%m_{Fe}=\dfrac{2,8}{5,2}\cdot100\%\approx53,85\%\\\%m_{Mg}=46,15\%\end{matrix}\right.\)
b) Theo các PTHH: \(\left\{{}\begin{matrix}n_{HCl\left(1\right)}=2n_{Fe}=0,1mol\\n_{HCl\left(2\right)}=2n_{Mg}=0,2mol\end{matrix}\right.\)
\(\Rightarrow\Sigma n_{HCl}=0,3mol\) \(\Rightarrow V_{HCl}=\dfrac{0,3}{1}=0,3\left(l\right)=300\left(ml\right)\)
