a, \(m_{hh}=m_{Al}+m_{Fe}=27n_{Al}+56n_{Fe}=11,1\left(I\right)\)
\(2Al+3H_2SO_4\rightarrow Al_2\left(SO_4\right)_3+3H_2\)
\(Fe+H_2SO_4\rightarrow FeSO_4+H_2\)
Theo PTHH : \(\dfrac{3}{2}n_{Al}+n_{Fe}=n_{H2}=0,3\left(II\right)\)
- Giair 1 và 2 => \(\left\{{}\begin{matrix}n_{Al}=0,1\\n_{Fe}=0,15\end{matrix}\right.\) mol
\(\Rightarrow\left\{{}\begin{matrix}m_{Al}=2,7g\left(24,32\%\right)\\m_{Fe}=8,4g\left(75,68\%\right)\end{matrix}\right.\)
b, - Theo PTHH : \(n_{H2SO4du}=n_{H2SO4}-n_{H2SO4pu}=0,325mol\)
\(\Rightarrow m_{H2SO4du}=31,85g\)
Ta có ; \(m_{dd}=m_{ddH2SO4}+m_{hh}-m_{H2}=255,5g\)
\(\Rightarrow\left\{{}\begin{matrix}C\%_{H2SO4}=\dfrac{m}{mdd}.100\%=12,46\%\\C\%_{Al2\left(SO4\right)3}=\dfrac{m}{mdd}.100\%=6,7\%\\C\%_{FeSO4}=\dfrac{m}{mdd}.100\%=8,9\%\end{matrix}\right.\)
Vậy ...
2Al+3H2SO4→Al2(SO4)3+3H2
Fe+H2SO4→FeSO4+H2
a,nH2=\(\dfrac{6,72}{22,4}\)=0,3(mol)
Gọi số mol của Al là x, số mol của Fe là y
Ta có :
27x+56y=11,1 (1)
1,5a+b=0,3 (2)
Từ (1),(2) ⇒x=0,1 ; y=0,15
%mAl=\(\dfrac{0,1.27}{11,1}.100\)=24,32%
%mFe=100%−24,32%=75,68%
b,nH2SO4=\(\dfrac{245.25\%}{98}\)=0,625(mol)
⇒nH2SO4.trong.Y=0,625−0,3=0,325(mol)
mdd(spu)=11,1+245−0,3.2=255,5(g)
nAl2(SO4)3=0,05(mol)
nFeSO4=0,15(mol)
⇒C%H2SO4=12,47%
C%Al2(SO4)3=6,2%
C%FeSO4=8,92%
