\(n_{CaCO_3}=\dfrac{50}{100}=0,5mol\\ Ca\left(OH\right)_2+CO_2\xrightarrow[]{}CaCO_3+H_2O\\ n_{CO_2}=n_{CaCO_3}=0,5mol\\ C_2H_5OH+3O_2\xrightarrow[]{}2CO_2+3H_2O\\ n_{C_2H_5OH}=\dfrac{1}{2}n_{CO_2}=0,25mol\\ m_{C_2H_5OH}=0,25.46=11,5g\\ V_{C_2H_5OH}=\dfrac{11,5}{1}=11,5ml\\ S=\dfrac{11,5}{30}\cdot100=38,33^0\)