\(n_{NaOH}=\frac{m}{M}=\frac{6,4}{40}=0,16\left(mol\right)\rightarrow n_{OH}=0,16\left(mol\right)\)
\(n_{CO_2}=\frac{V}{22,4}=\frac{1,568}{22,4}=0,07\left(mol\right)\)
Ta có tỉ lệ: \(\frac{n_{OH}}{n_{CO_2}}=\frac{0,16}{0,07}=2,28>2\rightarrow M_{th}\) (muối trung hòa)
\(PTHH:2NaOH+CO_2\rightarrow Na_2CO_3+H_2O\)
(mol) 2 1 1 1
(mol) 0,14 0,07 0,07 0,07
Tỉ lệ: \(\frac{0,16}{2}>\frac{0,07}{1}\Rightarrow NaOH.dư\)
\(m_{NaOH.dư}=n.M=\left(0,16-0,14\right).40=0,8\left(g\right)\)
\(m_{Na_2CO_3}=n.M=0,07.106=7,42\left(g\right)\)
\(n_{CO_2}=\frac{1,568}{22,4}=0,07\left(mol\right)\)
\(n_{NaOH}=\frac{6,4}{40}=0,16\left(mol\right)\)
CO2 + 2NaOH → Na2CO3 + H2O
a) Theo Pt: \(n_{CO_2}=\frac{1}{2}n_{NaOH}\)
Theo bài: \(n_{CO_2}=\frac{7}{16}n_{NaOH}\)
Vì \(\frac{7}{16}< \frac{1}{2}\) ⇒ NaOH dư
Theo pT: \(n_{NaOH}pư=2n_{CO_2}=2\times0,07=0,14\left(mol\right)\)
\(\Rightarrow n_{NaOH}dư=0,16-0,14=0,02\left(mol\right)\)
\(\Rightarrow m_{NaOH}dư=0,02\times40=0,8\left(g\right)\)
b) Theo pT: \(n_{Na_2CO_3}=n_{CO_2}=0,07\left(mol\right)\)
\(\Rightarrow m_{Na_2CO_3}=0,07\times106=7,42\left(g\right)\)
nCO2 = 1.568/22.4=0.07 mol
nNaOH = 6.4/40=0.16 mol
2NaOH + CO2 --> Na2CO3 + H2O
Bđ: 0.16_______0.07
Pư: 0.14_______0.07______0.07
Kt: 0.02_______0_________0.07
mNaOH dư = 0.02*40=0.8 g
mNa2CO3 = 0.07*106=7.42 g