a) Gọi $n_{MgO} = a(mol) ; n_{Al_2O_3} = b(mol) \Rightarrow 40a + 102b = 14,2(1)$
$n_{HCl} = \dfrac{182,5.20\%}{36,5} = 1(mol)$
$n_{HCl\ pư} = \dfrac{1}{100\% + 25\%} = 0,8(mol)$
$MgO + 2HCl \to MgCl_2 + H_2O$
$Al_2O_3 + 6HCl \to 2AlCl_3 + 3H_2O$
$n_{HCl} = 2a + 6b = 0,8(2)$
Từ (1)(2) suy ra a = b = 0,1
$\%m_{MgO} = \dfrac{0,1.40}{14,2}.100\% = 28,17\%$
$\%m_{Al_2O_3} = 100\% - 28,17\% = 71,83\%$
b)
$m_{dd\ sau\ pư} = 14,2 + 182,5 = 196,7(gam)$
$C\%_{MgCl_2} = \dfrac{0,1.95}{196,7}.100\% = 4,83\%$
$C\%_{AlCl_3} = \dfrac{0,1.133,5}{196,7}.100\% = 6,79\%$
$C\%_{HCl\ dư} = \dfrac{(1-0,8).36,5}{196,7}.100\% = 3,71\%$